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Web Services Essentials (O'Reilly XML) Review by Lee Bennett
Outdated but still a good overview
This is a well written overview for those that may have missed how Web Services rushed onto the scene earlier in the decade. Being 5 years old now, it is definitely out of date. I consider about 120 of 300 pages useful as an introduction to the subject to a developer who has been working in other technologies. It provides a good overview. The examples provided work well to illustrate the point presented. Keep in mind that the examples are outdated so skip liberally.
After reading/skimming this as an introduction, find a more current book for more hands on examples to work through in the technology you intend to use.